Regio- and enantioselective hydroamination of dienes by gold(I)/menthol cooperative catalysis.
نویسندگان
چکیده
Alcohol is key: regio- and enantioselective hydroamination of 1,3-dienes has been achieved with the dinuclear catalyst (R)-DTBM-SEGPHOS. The rate and selectivity of the reaction are enhanced by alcohol additives like menthol, which coordinates the cationic gold(I) to generate a Brønsted acid that can participate in catalysis. Mbs=p-methoxybenzenesulfonyl.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 50 42 شماره
صفحات -
تاریخ انتشار 2011